Upper Tagus loess formation and the marine atmosphere off the Iberian margin
Another area of the Southern Meseta, specifically the upper
catchment of the Guadiana River south of the Montes de
Toledo (Fig. 1), is characterized by having had less intense
surface erosion during the late Quaternary due to a higher
local base level of erosion. Here, the wetlands of the upper
Guadiana River represent a valuable Late Pleistocene archive
that is being intensively researched (e.g., Santisteban et al.,
2019). The sedimentary record of the Fuentillejo maar lake
in the volcanic field of Campo de Calatrava (Ortiz et al.,
2013) shows evidence of environmental fluctuations corre-
sponding to D-O cycles. More specifically, Vegas et al.
2010) found cold and ariıd conditions related to HE 2,
HE 1, and the Younger Dryas, whereas HEs 3-5 were
assumed to relate to rather warm and arid conditions. How-
ever, relatively low chronological resolution was the limiting
factor here. Finally, there are numerous playa lakes in the
Southern Meseta (Schütt, 2000). However, due to high salin-
ity and frequent desiccation events, these lake sediments
revealed a limited potential in recording last glacial paleoen-
vironmental evolution.
From this, it follows that reliable information about the
effect of marine cold spells linked to stadial phases on geo-
morphological systems in central Iberia is lacking, even
more if stadials comprising HEs (HS) are considered.
Hence, there is a need for systematic studies on fluvial, aeo-
lian, and glacial sedimentary archives relating to relevant
past earth surface processes. In order to meet this need and
(O verify whether Greenland stadials as well as Heinrich sta-
dials exercised a decisive influence on geomorphological sys-
;ems, we undertook comprehensive studies on loess deposits
in the upper Tagus Basin to obtain a more complete picture of
late Pleistocene landscape dynamics in central Spain. Besides
a general evaluation of phases linked to loess deposition and
surface stability, we used a broad multi-proxy approach in
order to accurately characterize hydrological conditions, pale-
otemperatures, and wind strengths during the last glacial
period.
METHODS
Stratigraphic work
In total, five loess sections were included in this study in order
to obtain a representative composite profile for the last glacial
period (Fig. 1). All sections were analyzed in the field, includ-
ing differentiation of sedimentary units, the presence of pale-
0sols or processes indicating soil formation, and evidence for
relocation processes. We took samples from all sections for
laboratory analyses. In general, sampling was oriented
towards stratigraphic layers with the aim of providing a repre-
sentative record of all dynamic phases during the last glacial
period. On average, samples for standard analyses were taken
at 15 cm intervals from all sections. We took 28 samples for
heavy mineral analyses from each layer in three sections
(Fuentiduena, Paraiso, and A3). We also took seven samples
from surrounding areas (for more details, see Wolf et al.,
2019). The same three sections sampled for heavy mineral
analysis were also chosen for luminescence dating on 25 sam-
ples. The most complete section (Paraiso) was sampled for
n-alkane biomarker analyses and stable isotope measure-
ments, with 25 samples with an average sampling density
of 25 cm taken.
Standard analyses
Srain-size determination was conducted by pipette analyses
and wet sieve techniques (Schlichting et al., 1995) after dis-
Jersion with sodium pyrophosphate. Because samples con-
:ained gypsum that disrupted the settling process in the
sample cylinder by flocculation, all samples were passed
hrough a repeated cycle of dissolution and centrifugation
ıntil measured electrical conductivity fell below a value of
100 uS cm” (Frenkel et al., 1986). For determining
fraction-specific carbonate contents for different grain-size
classes, we conducted grain-size analysis twice, with a first
un implemented without decalcification, and a second run
after carbonates were dissolved using 10% HCl. Following
his procedure, a particle size index (PSI) was calculated
3ased on samples that were not decalcified by forming a
:atio between the coarse silt/fine sand fractions (> 20 um
ınd < 200 um) and all finer fractions, including medium
silt, fine silt, and clay. The calcium carbonate content was
determined by measuring the carbon dioxide gas volume
after adding hydrochloric acid in a Scheibler apparatus
‘Schlichting et al., 1995). Soil organic matter was measured
via suspension and catalytic oxidation (TOC-VCPN/DIN
[SO 16904). Total iron content (Fe(t)-values) was determined
after pressure digestion with concentrated nitric and hydroflu-
oric acid using atomic adsorption spectrometry (Analytic
Jena, Vario 6). Pedogenic iron content (Fe(d)-values) was
neasured after dithionite extraction using atomic adsorption
spectrometry (Schlichting et al., 1995). The ratio between
nedogenic and total iron may provide information of the
intensity of weathering, and thus may indicate soil formation
in the case of higher values in comparison to the parent
material.
Micromorphological analyses
For micromorphological analyses, 18 oriented and undis-
urbed samples were collected from selected horizons of the
sequences at Paraiso and Fuentiduena. Vertical thin sections
were prepared at the Laboratory of Soil Science and Geoecol-
ogy at the Institute of Geography, Eberhard-Karls-University,
Tübingen. Thin sections were then analyzed and photo-
zraphed using a polarizing microscope (Zeiss Axiovision).
Thin section descriptions mainly are based on the terminol-
ogy after Bullock et al. (1985) and Stoops (2003).
Age determination: luminescence dating
Optically stimulated luminescence (OSL) measurements
were applied to the coarse-grained quartz fraction (90-200
um). Following standard procedures (e.g., Fuchs et al.,
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