163
Table 63: Physico-chemical properties of trifluralin.
Parameter
CAS number
1582-09-8
Log K 0 w
5.3 a
Log K oc [L/kg]
3.8-4.1 a
Solubility in water [mg/L]
0.19 a
Biodegradation
months b
Vapour pressure [Pa]
9.5xl0" 3 a
Atmospheric half-life [d]
0.22 a
Data from: a (OSPAR Background Document on Trifluralin, 2004); b (Lerche et al. 2002)
Acute toxicity for mammals is relatively low (LD 5 o-value = 10000 mg/kg body weight
rat (Rompp, 1995)). In contrast, the acute ecotoxicity effects on maritime unicellular
algae are high (Walsh, 1972). NOEC values for different types of aquatic organisms
vary on the order of 1-100 pg/L (see Table 64). No information is presently available on
the chronic toxicity of trifluralin to organisms in the marine environment.
Table 64: Survey of acute / chronic toxicity of trifluralin to aquatic organisms.
Aquatic organism
Species
Value/period [d]
Cone. [pg/L]
algae
Chlorococcum sp.
EC50/-
2.5 b
crustacean
Daphnia magna
NOEC/64
2.4 a
fish
Pimephales promelas
NOEC/35 spinal cord
deformation
0.3 a
Data from; “(Data sheet on Trifluralin); b (Walsh, 1972)
Unlike data on trifluralin concentrations in surface, ground and drinking water,
information about levels in sea water is scarce. Analyses of samples from the North and
Baltic Seas in 1997-1999 showed trifluralin concentrations of <0.02-0.05 ng/L (North
Sea) and <0.02-0.06 ng/L (Baltic Sea) (Meeresumweltdatenbank (MUDAB)). The limit
of quantification was 0.02 ng/L. The distribution of trifluralin is relatively uniform, with
samples from the open sea occasionally having slightly higher concentrations than those
from the coastal waters. In contrast to the low concentrations found in the North and
Baltic Seas, concentrations in the North Pacific Ocean were 100 times higher. In 1993,
Chernyak found a trifluralin concentration of 1.15 ng/L in that area (limit of