156
Table 54: Physico-chemical properties of dicofol.
Parameter
CAS number
115-32-2
Log Kow
5.0 a , 3.54 b
Solubility in water [mg/L]
1.2 (24°C) C
Biodegradation
> months 3
Vapour pressure [Pa]
1.6xl0" 6 3
Half-life in water
pH 7: 4 d, pH 9: 0.02 d
Half-life in soil
pH 7: 30-35 d
Atmospheric half-life [d]
3.1 d 3
Data from: “(Lerche et ah, 2002), b (www.inchem.org). c (OSPAR Background Document on dicofol)
The high log K ow value of 3.5 - 5.0 (see Table 54) indicates an affinity of dicofol to
accumulate in sediments and biological tissues. The acute oral toxicity of dicofol is
690 mg/kg body weight rat (LD^o-value) (Römpp, 1995). It has been classified by the
World Health Organisation as a Class III “slightly hazardous” pesticide (pan-uk, 1999).
Within the framework of this study, dicofol and its degradation product 4,4’-
dichlorobenzophenone (Figure 25) were screened for teratogenic effects by Kamman
(Kammann, 2004) (see Chapter 6.4.6.2): effects were found for dicofol at
concentrations of 2-10 mg/L; no effects were observed for dichlorobenzophenone.
Table 55 gives an overview of acute dicofol toxicity to organisms in the marine
environment. No data are available on chronic toxicity following exposure to low
concentrations for several years, particularly with respect to marine aquatic organisms.
Table 55: Survey of acute / chronic toxicity of dicofol to aquatic organisms.
Aquatic organism
Value/period [d]
Cone. [pg/L]
Algae
LC50/acute
73.0
Crustacean
LC50/acute
80.0
Mollusc
LC50/acute
15.0
Fish
LC50/300
4.5
Data from: (OSPAR Background document on dicofol)