119
Table 37: Relative abundance of s- and mPCA formula and congener groups (C10.15CI5.10), calculated
molecular weight, chlorine content and main components in sediments and suspended matter from rivers.
Determination was carried out by HRGC-ECNI-LRMS.
Molecular weight % Cl Relative Abundance Main component
sPCA mPCA sPCA mPCA C u Cn C l2 C u C l4 C15 sPCA mPCA
River sediments
Seine 1
414
451
61
56
9
36
31
25
74
26
u
0
0
0
Seine 2
381
445
58
56
12
36
21
30
61
39
C„C1 7
C 14 C1 7
Seine 3
419
448
61
56
12
26
31
30
71
29
C„C1 V
C14C1-7
Hamburg 1
447
442
65
55
9
45
31
16
59
41
C„C1 8
C 14 C1 7
Hamburg 2
440
435
64
55
5
32
43
20
61
39
c 12 ci 8
C 14 C1 6
Hamburg 3
414
441
64
55
39
28
23
10
59
41
C10C17
C 14 C1 7
Tromsp 1
424
446
63
53
9
38
33
20
66
34
C„C1 7
C 14 C1 7
Tromsp 2
429
453
62
57
10
24
37
30
60
40
C 12 C1 8
C 14 C1 7
Suspended particulate matter
Elbe
421
437
63
55
19
42
29
10
54
46
C„C1 7
C15C16
Neckar 1, km 8
5.8.2002
426
465
63
58
12
36
32
21
69
31
C„C1 7
C 14 C1 8
2.9.2002
423
460
63
57
12
39
32
17
67
33
C„C1 7
C 14 C1 8
25.11.2002
424
458
63
57
21
35
28
16
79
21
C„C1 7
Ci 4 Cl 7 / 8
16.12.2002
433
465
63
58
10
34
32
23
74
26
C 12 C1 8
C 14 Cl 7/8
Rhine, km 334
6.8.2002
429
455
63
57
11
30
36
24
65
35
C 12 C1 7
C 14 C1 7
4.9.2002
421
460
62
57
10
29
34
27
60
40
C12C17
C14C17
18.12.2003
429
452
63
57
12
33
36
20
71
29
C 12 C1 8
C 14 C1 7